preparation and characterization of 2-(methylamino) pyridine complex of cu(i)
نویسندگان
چکیده
2-(methylamino) pyridine (hmap) reacts with meli in thf and generates the lithium salt (limap). further reaction of [cu(tmeds)2][cucl2] (tmeda=tetramethylethylenediamine) with one equivalent of this ligand in thf leads to the formation of a yellow dimeric cu(i) complex, [cu(map)]2. analytical data, molecular weight, and magnetic susceptibility measurements, confirm the formula [cu(map)]2 .
منابع مشابه
Preparation and Characterization of 2-(Methylamino) Pyridine Complex of Cu(I)
2-(Methylamino) pyridine (HMAP) reacts with MeLi in THF and generates the lithium salt (LiMAP). Further reaction of [Cu(TMEDS)2][CuCl2] (TMEDA=tetramethylethylenediamine) with one equivalent of this ligand in THF leads to the formation of a yellow dimeric Cu(I) complex, [Cu(MAP)]2. Analytical data, molecular weight, and magnetic susceptibility measurements, ...
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عنوان ژورنال:
iranian journal of chemistry and chemical engineering (ijcce)ناشر: iranian institute of research and development in chemical industries (irdci)-acecr
ISSN 1021-9986
دوره 14
شماره 1 1995
میزبانی شده توسط پلتفرم ابری doprax.com
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